Organofluorine Chemistry
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62.Copper-Mediated Fluoroalkylation Reactions with Iododifluoroacetamides: Controlling the Selectivity among Cross-Coupling, Intramolecular Cyclization, and Homocoupling Reactions  
  Zhu, Jieming; Zhang, Wei; Zhang, Laijun; Liu, Jun; Zheng, Ji; Hu, Jinbo*
J. Org. Chem. 2010, 75, 5505-5512.
PRO_201522740636.jpg
61.Highly Diastereoselective Synthesis of α-Difluoromethyl Amines from N-tert-Butylsulfinyl Ketimines and Difluoromethyl Phenyl Sulfone  
  Liu, Jun; Hu, Jinbo*
Chem. Eur. J. 2010, 16, 11443-11454.
PRO_2013121897118.gif
60.Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones  
  Zhao, Yanchuan; Huang, Weizhou; Zhu, Lingui; Hu, Jinbo*
Org. Lett. 2010, 12, 1444-1447.
PRO_20163335350.jpg

  31.gif

 ["2-PySO2CF2H" was referred to as "Hu reagent", see ACIE 2013 &  ACIE 2016]

[A study question on 2-PySO2CF2Hadapted from a textbook Organic and Inorganic Fluorine Chemistry]


59.Magnesium Metal-Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone  
  Zhao, Yanchuan; Zhu, Jieming; Ni, Chuanfa; Hu, Jinbo*
Synthesis, 2010, 1899-1904.
PRO_201451342008.jpg
58.1-tert-Butyl-1H-tetrazol-5-yl Fluoromethyl Sulfone (TBTSO2CH2F): A Versatile Fluoromethylidene Synthon and Its Use in the Synthesis of Monofluorinated Alkenes via Julia-Kocienski Olefination  
  Zhu, Lingui; Ni, Chuanfa; Zhao, Yanchuan; Hu, Jinbo*
Tetrahedron, 2010, 66, 5089-5100.
PRO_2013121841740.gif
57.Highly Stereoselective Synthesis of Monofluoroalkenes from α-Fluorosulfoximines and Nitrones  
  Zhang, Wei; Huang, Weizhou; Hu, Jinbo*
Angew. Chem. Int. Ed. 2009, 48, 9858-9861.
(《有机化学》亮点介绍)
PRO_2013121849967.gif
56.Palladium/Acetic Acid-Catalyzed Fluoroalkylation of Alkynes with Monofluorinated Sulfones as Pronucleophiles  
  Ni, Chuanfa; Hu, Jinbo*
Tetrahedron Lett. 2009, 50, 7252-7255.
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55.Selective Difluoromethylation and Monofluoromethylation Reactions  
  Hu, Jinbo*; Zhang, Wei; Wang, Fei
Chem. Comm. 2009, 7465-7478.
PRO_2013121865406.gif
54.Nucleophilic, Radical, and Electrophilic (Phenylsulfonyl)difluoromethylations  
  Hu, Jinbo*
J. Fluorine Chem. 2009, 130, 1130-1139.
PRO_201491870611.gif
53.Synthesis of Fluorinated Chiral Amines Using N-tert-Butylsulfinyl Imines  
  Liu, Jun; Hu, Jinbo*
Future Medicinal Chemistry, 2009, 1, 875-888.
PRO_2020121843258.jpg
52.N-Tosyl-S-Difluoromethyl-S-Phenyl Sulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles  
  Zhang, Wei, Wang, Fei; Hu, Jinbo*
Org. Lett. 2009, 11, 2109-2112.
PRO_20163335350.jpg
51.Synthesis of Fluorinated β-Ketosulfones and gem-Disulfones by Nucleophilic Fluoroalkylations of Esters and Sulfinates with Di- and Monofluoromethyl Sulfones  
  Ni, Chuanfa; Zhang, Laijun; Hu, Jinbo*
J. Org. Chem. 2009, 74, 3767-3771.
PRO_201522719780.jpg
50.C-F Bond Cleavage by Intramolecular SN2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles  
  Zhang, Laijun; Zhang, Wei; Liu, Jun; Hu, Jinbo*
J. Org. Chem. 2009, 74, 2850-2853.
PRO_201522724428.jpg
49.Bronsted Acid Mediated (sp3)Carbon-Fluorine Bond Activation: Inter- and Intramolecular Arylation of Trifluoromethylated Arenes  
  Wang, Fei; Hu, Jinbo*
Chin. J. Chem. 2009, 27, 93-98.
PRO_2013121816482.gif
48.Free Radical (Phenylsulfonyl)difluoromethylation of Alkynes with PhSO2CF2I Reagent: Stereoselective Preparation of PhSO2CF2- and CF2H-Substituted Alkenes  
  Li, Ya; Li, Huaifeng; Hu, Jinbo*
Tetrahedron, 2009, 65, 478-483.
PRO_2013121879521.gif


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