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92. Silver-Mediated Trifluoromethylation？Iodination of Arynes
Zeng, Yuwen; Zhang, Laijun; Zhao, Yanchuan; Ni, Chuanfa; Zhao, Jingwei; Hu, Jinbo*
J. Am. Chem. Soc. 2013, 135, 2955？2958.
(Highlighted by Synfacts 2013, 9(5), 544.)
(Highlighted by Org. Process R...
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91. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group
Zhao, Yanchuan; Gao, Bing; Ni, Chuanfa; Hu, Jinbo*
Org. Lett. 2012, 14, 6080-6083.
(Highlighted by Synfacts 2013, 9(3), 312)
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90. Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones
Shen, Xiao; Zhang, Wei; Ni, Chuanfa; Gu, Yucheng; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 16999-17002.
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89. Copper-Mediated Trifluoromethylation of α-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter
Hu, Mingyou; Ni, Chuanfa; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 15257-15260.
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88. Copper-Catalyzed Difluoromethylation of β,γ-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation
He, Zhengbiao; Hu, Mingyou; Luo, Tao; Li, Lingchun; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 11545-11547.
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87. Enantioselective Construction of Fluorinated Tertiary Stereogenic Carbon Centers in Cyclopropanes: A Chiral α-Fluoro Carbanion Strategy
Shen, Xiao; Zhang, Wei; Zhang, Lei; Luo, Tao; Wan, Xiaolong; Gu, Yucheng; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 6966-6970.
(Highlighted by Organic Chemistry Portal, Dec. 30, 2013)
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86. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds
Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Am. Chem. Soc. 2012, 134, 5790-5793.
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85. Copper-Catalyzed Di- and Trifluoromethylation of α,β-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations
He, Zhengbiao; Luo, Tao; Hu, Mingyou; Cao, Yanjing; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 3944-3947.
（被《有机化学》亮点介绍）
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84. Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters
Zhao, Yanchuan; Hu, Jinbo*
Angew. Chem. Int. Ed. 2012, 51, 1033-1036.
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83. Palladium-Catalyzed Allylation of 2,2,2-Trifluoroethyl Phenyl Sulfone: A Potential 2,2,2-Trifluoroethyl Pronucleophile
Zhang, Wei; Zhao, Yanchuan; Ni, Chuanfa; Mathew, Thomas*; Hu, Jinbo*
Tetrahedron Lett. 2012, 53, 6565-6568.
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82. Nucleophilic Fluoroalkylation of a,β-Unsaturated Carbonyls with α-Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts
Shen, Xiao; Ni, Chuanfa; Hu, Jinbo*
HeIv. Chim. Acta, 2012, 95, 2043-2051.
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81. Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions
Kosobokov, M. D.; Dilamn, A. D.*; Struchkova, M. I.; Belyakov, P. A.; Hu, Jinbo
Journal of Organic Chemistry, 2012, 77, 2080-2086.
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80. Nucleophilic Difluoromethylation of C=N Bonds in Heterocycles with Difluoromethyl Silane Reagents
Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Zhang, Wei; Dilman, Alexander, D.; Hu, Jinbo*
Tetrahedron, 2012, 68, 5137-5144.
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79.Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te)
Hu, Mingyou; Wang, Fei; Zhao, Yanchuan; He, Zhengbiao; Hu, Jinbo*
J. Fluorine Chem. 2012, 135, 45-58.
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78.Nucleophilic Difluoromethylation of N,N-Acetals with TMSCF2SO2Ph Reagent Promoted by Trifluoroacetic Acid: A Facile Access to α-Difluoromethylated Tertiary Amines
Huang, Weizhou; Ni, Chuanfa; Zhao, Yanchuan; Gao, Bing; Hu, Jinbo*
J. Fluorine Chem. 2012, 143, 161-166.
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