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219.Controllable Single and Double Difluoromethylene Insertions into C-Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF2H and TMSCF2Br
Xiu Wang, Shitao Pan, Qinyu Luo, Qian Wang, Chuanfa Ni, and Jinbo Hu*
J. Am. Chem. Soc.2022, 144, 12202–12211.
(Highlighted in JACS Spotlight)
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218.Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent
Ran Liu and Jinbo Hu*
Org. Lett. 2022, 24, 3589-3593
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217.Copper-mediated pentafluoroethylation of organoboronates and terminal alkynes with TMSCF3
Pan, Shitao; Xie, Qiqiang; Wang, Xiu; Wang, Qian; Ni, Chuanfa; Hu, Jinbo*
Chemical Communications, 2022, 58, 5156-5159.
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216.SulfoxFluor-Enabled Deoxyazidation of Alcohols with NaN3
Guo, Junkai; Wang, Xiu; Ni, Chuanfa; Wan, Xiaolong; Hu, Jinbo*
Nature Communications, 2022, 13, e2752.
(J.G. and X.W. contributed equally to this work)
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215.Modified and Scalable Synthesis of N-Tosyl-4-Chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor): Direct Imidation of Sulfinyl Chlorides with Chloramine-T Trihydrate
Liu, Renxiang; Zhou, Xiao-Cong; He, Xin-Yi; Li, Yuan-Qiang;* Zheng, Weiqin; Wang, Xiu; Guo, Junkai; Ni, Chuanfa;* Hu, Jinbo*
Org. Process Res. Dev. 2022, 26, 380-386.
(Featured on the Cover)
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214.Cover Profile: S-(Trifluoromethyl) Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation
Meng, Depei; Lyu, Yichong; Ni, Chuanfa; Zhou, Min; Li, Yang; Hu, Jinbo*
Chemistry-A European Journal 2022, 28, e202200483.
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213.S-(Trifluoromethyl) Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation
Meng, Depei; Lyu, Yichong; Ni, Chuanfa; Zhou, Min; Li, Yang; Hu, Jinbo*
Chemistry-A European Journal 2022,28, e202104395.
(Very important paper)
(Featured on the Cover)(Featured by WileyChem-China)
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212.Difluoromethyl 2-Pyridyl Sulfoximine: A Stereoselective Nucleophilic Reagent for Difluoro(aminosulfinyl)methylation and Difluoro(aminosulfonyl)methylation
Liu, Qinghe; Ni, Chuanfa; Wang, Qian; Meng, Depei; Hu, Jinbo*
CCS Chem.2022,4,3648–3659
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211.TMSCF2Br-Enabled Fluorination-Aminocarbonylation of Aldehydes: Modular Access to α-Fluoroamides
Liu, An; Ni, Chuanfa; Xie, Qiqiang; Hu, Jinbo*
Angew. Chem.Int. Ed.2022,61, e202115467.
(Featured by X-MOL)
(Featured by WileyChem-China)
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210.Photoredox-Catalyzed Ring-Opening Addition Reaction between Benzyl Bromides and Cyclic Ethers
Cuiwen Kuang,Chuanfa Ni, Yucheng Gu, Jinbo Hu*
Synthesis 2021,54,1272-1286
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209.Water-promoted regio-selective trifluoromethylation of vinyl conjugated diazoacetates
Xinxin Han, Xin Liu, Yueyun Bao, Hunahuan Song, Yu-Rou Zhao, Xiaoying Wang,Junjie Zhang, Le Liu, Xin-Hua Duan, Jinbo Hu and Mingyou Hu*
Org. Chem. Front., 2022, 9, 204–209
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208.Fluorination Triggers Fluoroalkylation: Nucleophilic Perfluoro-tertbutylation with 1,1-Dibromo-2,2-bis(trifluoromethyl)ethylene (DBBF) and CsF
Qian Wang, Quan Tao, Hui Dong, Chuanfa Ni, Xiaoming Xie,* and Jinbo Hu*
Angew. Chem. Int. Ed. 2021, 60, 27318 –27323
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207.Difluorocarbene-Induced Ring-Opening Difluoromethylation-Halogenation of Cyclic (Thio)Ethers with TMSCF2X (X = Br, Cl)
Zhang, Rongyi; Li, Qigang; Xie, Qiqiang; Ni, Chuanfa*; Hu, Jinbo*
Chemistry？A European Journal, 2021, 27, 17773–17779.
(Featured by WileyChem-China)
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206. Divergent S- and C-Difluoromethylation of 2-Substituted Benzothiazoles
Wang, Xiu; Ye, Wenchao; Kong, Taige; Wang, Chenlu; Ni, Chuanfa; Jinbo Hu*
Organic Letters 2021, 23, 8554–8558.
(X.W. and W.Y. contributed equally to this work)
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205. Nucleophilic Trifluoromethylation of Azinium Salts with Zn(CF3)2 bpy
Pan, Shitao; Wang, Xiu; Ni, Chuanfa; Hu, Jinbo*
Tetrahedron 2021, 100, e132477.
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